Solutions for Drude model exercises¶
Exercise 1: Extracting quantities from basic Hall measurements¶
-
The Hall voltage is measured across the sample width. It is given by
\[ V_H = V(W)-V(0) = -\int_{0}^{W} E_ydy = -E_y W \]From the steady-state solution of the Drude equation of motion, we obtain $E_y = \rho_{yx}j_x = \frac{-B}{ne}j_x $. Using \(j_x = I_x / W\) and \(V_H=-E_y W\), we obtain \(R_{yx} = V_H/I_x = \frac{B}{ne}\). so it does not depend on the sample geometry.
-
If the hall resistance and the magnetic field are known, we extract the charge density using \(R_{yx} = \frac{B}{ne}\). Because \(V_H = \frac{B}{ne}I_x\), a stronger field yields a larger Hall voltage, making it easier to measure. Likewise, a lower charge density yields a larger Hall voltage for a given bias current, making it easier to measure.
-
The longitudinal resistance is
\[ R_{xx} = \rho_{xx}\frac{L}{W} \]with \(\rho_{xx} = \frac{m_e}{ne^2\tau}\) the longitudinal Drude resistivity. Therefore, knowing the electron density \(n\), we can extract the scattering time (\(\tau\)). We observe that \(R_{xx}\) depends on the sample geometry (\(L\) and \(W\)), whereas the Hall resistance \(R_{yx}\) does not.
Exercise 2: Temperature dependence of resistance in the Drude model¶
- We first find the electron density using \(n_e = \frac{ZnN_A}{W}\), where \(Z=1\) is the number of free electrons per copper atom, n is the mass density of copper, \(N_A\) is Avogadro's constant, and W is the atomic weight of copper. Then, we find the scattering time \(\tau = 2.57 \cdot 10^{-14}\) s from the longitudinal Drude resistivity \(\rho = \frac{m_e}{n_e e^2\tau}\).
- Using \(\lambda = \langle v \rangle\tau\), we get \(\lambda =3\) nm.
- The scattering time \(\tau \propto \frac{1}{\sqrt{T}}\), such that we expect \(\rho \propto \sqrt{T}\).
- For most metals, the measured resistivity scales as \(\rho \propto T\), in contrast with the \(\rho \propto \sqrt{T}\) predicted by the Drude model. The linear scaling can be understood by assuming that the scattering is caused by phonons, as their number scales linearly with T at high temperature (recall that the high-temperature limit of the Bose-Einstein distribution functions is \(n_B = \frac{kT}{\hbar\omega}\) leading to \(\rho \propto T\)). The inability to explain this linear dependence is a failure of the Drude model.
Exercise 3: The Hall conductivity matrix and the Hall coefficient¶
-
\(\rho_{xx}\) is independent of B and \(\rho_{xy} \propto B\)
-
The conductivities are
\[ \sigma_{xx} = \frac{\rho_{xx}}{\rho_{xx}^2 + \rho_{xy}^2} = \frac{mne^2\tau}{m^2+e^2\tau^2 B^2} \]\[ \sigma_{xy} = \frac{-\rho_{yx}}{\rho_{xx}^2 + \rho_{xy}^2} = \frac{Bne^3 \tau^2}{m^2+e^2 \tau^2 B^2} \] -
These equations describe Lorentzian-like functions.
-
The Hall coefficient is \(R_H = -\frac{1}{ne}\). The sign of the Hall coefficient depends on sign of the charge carriers (analyzed further in the next exercise).
Exercise 4. Positve and negative charge carriers¶
-
The current is the sum of the currents carried by the positive and negative charge carriers:
\[ \mathbf{J} = -n_e e \mathbf{ v_e} + n_h e \mathbf{ v_h} \] -
Write down the Drude equation of motion for the positive and negative charge carriers separately and use $ \mu_e = \frac{e\tau_e}{m_e}$ and $ \mu_h = \frac{e\tau_h}{m_h}$
-
From the assumption, we can ignore the \((\mathbf{ v_i} \times \mathbf{B})_x\) terms. Then combining question 1 and 2 gives the result.
-
The net current in the y-direction should be zero.
-
The Hall coefficient is
$$ R_H = \frac{n_h\mu_h^2 - n_e\mu_e^2}{e(n_h\mu_h + n_e \mu_e)^2} $$ We observe that the sign of \(R_H\) is determined by the density and the mobilty of the positive and negative charge carriers. Therefore, a measurement of the Hall voltage reveals the dominant charge carrier.